Mehrere Mitteln
Phenol
Phenolengruppe
Alth und andere Pflanzen enthalten Phenolsäure
Arbin wird im Darm durch Bakterien zu Glucose und Hydrochinon umgesetzt
Ben hat ähnliche Formel
Brachinus = Bombardierkäfer/verteidigt sich durch Spritzen von Hydrochinon gemischt mit Wasserstoffperoxid Coleoptera
Carbol-ac. Enthält Phenol
Kres = Produkt aus Buchenteer/enthält 5% Phenol
Pic-ac = Trinitrophenolum
Tan-ac = Phenol/=
Gerbsäure
Vitis R
Geschmacksträger in Whisky (= rauchiger Geschmack).
Quinone
From
Wikipedia, the free encyclopedia
Not to be
confused with quinine.
A quinone
is a class of organic compounds that are formally "derived from aromatic
compounds [such as benzene or naphthalene] by conversion of an even number of
–CH= groups into –C(=O)– groups
with any
necessary rearrangement of double bonds," resulting in "a fully
conjugated cyclic dione structure."[1] The class includes some
heterocyclic compounds.
The
prototypical member of the class are 1,4-benzoquinone or cyclohexadienedione,
often called simply quinone (whence the name of the class). Other important
examples are 1,2-benzoquinone
(ortho-quinone),
1,4-naphthoquinone and 9,10-anthraquinone.
Quinones
are oxidised derivatives of aromatic compounds and are often readily made from
reactive aromatic compounds with electron-donating substituents such as phenols
and catechols, which
increase
the nucleophilicity of the ring and contributes to the large redox potential
needed to break aromaticity. (Quinones are conjugated but not aromatic).
Quinones are electrophilic Michael
acceptors
stabilised by conjugation. Depending on the quinone and the site of reduction,
reduction can either rearomatise the compound or break the conjugation.
Conjugate addition nearly always
breaks the conjugation.
Chinone sind eine große und wichtige Gruppe organischer Verbindungen, die als Oxidationsprodukte von Aromaten, insbesondere von Phenolen, aufgefasst werden können. Der Name Chinon leitet
sich von der Chinasäure ab, deren Oxidation u. a. zu 1,4-Benzochinon führt. Chinone sind Benzolderivate, in denen unter Aufhebung der Aromatizität des Ringes an zwei Kohlenstoffatomen die
Substituenten durch doppelbindigen Sauerstoff ersetzt sind. Stoffe, deren chemische Struktur ein Chinon-Element enthält, nennt man chinoid, das Strukturelement selbst chinoides System.
Die Reduktion von Chinonen liefert die zugehörigen Phenole, die auch Chinole genannt werden.
Die durchweg farbigen Chinone sind Oxidationsmittel, deren Redoxpotential durch Substituenten (Halogen-, Cyan-, Alkyl-, Hydroxy-Gruppen) deutlich verändert wird. Man unterscheidet
1,2-(ortho-)Chinonen (z. B. PQQ) und 1,4-(para-)Chinonen (z. B. Anthrachinon).
Formaler Ersatz des Sauerstoffs einer chinoiden Carbonyl-Gruppe durch =NH, =NOH, =N2 oder =CH2 führt zu Chinoniminen, Chinonoximen, Chinondiaziden und Chinonmethiden.
Synonym bezeichnet Chinon die Verbindung 1,4-Benzochinon, die durch Oxidation aus 1,4-Dihydroxybenzol (Hydrochinon) entsteht.
Unter den Chinonen finden sich viele Gifte, aber auch ein breites Spektrum lebensnotwendiger Vitalstoffe, z. B. Ubichinone, Phyllochinone, PQQ.
Bekannte Chinone sind:
die Ubichinone als Elektronenüberträger in der Atmungskette
die Plastochinone bei der Photosynthese
die K-Vitamine (Phyllochinon, Menachinon)
das Pyrrolochinolinchinon (PQQ)
das Tryptophantryptophylchinon (TQQ)
das Dichlordicyanochinon (DDQ)
die Hydroxynaphthochinone (in Henna und Walnüssen)
Echinochrom A, Adrenochrom, Dopachrom
Chinone werden auch in den Wehrsekreten von Insekten: gefunden.
Naphthoquinone = Naphtachinon (Naphtoc) = Lawsone/= natural orange/=
Juglon-ähnlich (= Teil Jug-r)/C10H6O2
Repertorium:
Kopf: Tumoren im Gehirn schnell wachsend
Gesicht: bläuliche Lippen
Bauch: Darmkrebs
Nieren: Degeneration/Polyzystische Nierendegeneration - stark ausgeprägt
Blase: Krebs - schmerzhaft, qualvoll
Prostata: Entzündet
Krebs
Atmung: Asthma, asthmatische Atmung bei Rauchern
Brust: Entzündete Mammae
Zyanose
Beschwerden der Aortenklappe - Stenose
Allgemeines: Konvulsionen epileptisch - traumatisch
unzureichende Funktion der Nebenniere
Vergleich. Enthalten in: Lawsonia (allergen/Hennatattoo) + Impatiens balsamica (= jewelweed/Geraniales);
Siehe: Farbstoffen
Allerlei: verursacht Anämie/absorbiert UV.
obtained by
oxidizing naphthalene with Chr-ac
Important
Proving Symptoms and Themes Noted by the Investigators
Affecting
sleep patterns (easy falling asleep/restless and increased remembrance of
dreams)
Headache
“Like a band”. Improvement of premenstrual abdominal distension and swelling
(limbs/premenstrual spotting)/waking to urinate
Diarrhea
Repertory:
Mind: Dreams – red colored
(cars/flags)/being pursued/silly/remembered (throughout the day)/vivid
Dull
mind/unclear thoughts when feverish
Worried
Feeling
smart, confident, intelligent
Talking in
sleep person awakens without remembering
Waking with
weeping after a dream
Anxious
(and apprehension/”As if time moved too slowly)
Generalities: Desires: ice-cold
things/salad/chocolate;
Feeling
shaky and jittery “As from a reaction to diet medication”
Lethargic
Premenstrual
symptoms decrease: less bloating and swelling
Engorgement
of blood vessels
Vertigo: Dizzy after eating, with a relaxed
and floating sensation
Head: Pain – stitching/sharp and
stabbing in forehead/sharp shooting on r. vertex/piercing/pressing “Like a cap”
is dull constant pain/raging “Like a vise” on waking/
stitching
in forehead/sharp, shooting at vertex/pressing “Like a cap”/dull/piercing
Eye: Uncontrollable twitching of r. lid
Ear: Wax bright yellow
Hearing: “As if plugged”/”As if sound is
less perceived”
Nose: Increased mucus in postnasal
passages
Tickling
internal leads to sneezing
Face: Cold sore in the r. corner of
mouth
Mouth: Aphthae on r. side of mouth
Soreness on
the tongue like a swollen taste bud or “As from biting”
Biting the
inside of the mouth when talking.
Teeth: Tooth sensitive to hot and cold
Throat: Dryness internal < at bedtime
Euphoric
feeling in throat “As if tingling”
Scratchy
sensation of throat with postnasal mucus
Clears
throat in evening
Stomach: Thinking of food causes desire to
gag
Increased
hunger
Abdominal
cramps with nausea in the evening
Growling
Abdomen: “As if a hole like an empty
cavity”
Pain - dull
above the umbilicus/cramping with nausea and cold perspiration/aching followed
by bowel movements
Swelling
and distended before menses
Rectum: Feeling of incomplete evacuation
after a bowel movement
Flatus with
involuntary stool
Diarrhea on
waking, or causes rushing to the toilet
Intense
itching in the anus
Stool: Diarrhea with foul-smelling stool
Stool: starts solid and becomes more
liquid.
Rushing to
the toilet with runny, loose stools
Female
organs: Spotting preceding
menstrual flow
Menses
starts and suddenly
Cramping
before or during menses
Respiration:
Speech and
Voice: Hoarse towards evening
Chest: Breast swollen for menses and
painful/tender
Back: “Neck as if swollen” with dullness
of the mind.
Neck and back
- left-sided tightness ext. to hamstrings and calves
Limbs: Stiffness and aching in ankle and
elbow joints
Muscles
tight l. sided ext. from neck and back to hamstrings and calves
Swollen
hand/fingers/ankle before menses
Pain –
cramp in l. calf on waking at night
Sleep: Falling asleep early in the
evening
Restless
with tossing and turning
Getting hot
during sleep and throwing off the covers
Need to
wake during the night to urinate
Sleeps on
the back
Skin: Moles on neck
Picricum
acidum (Pic-ac) = TNP/= Trinirophenol/= C6H3N3O7
Hydroquinone (Hydroq) = Hydrochinon/= Phenol
Repertorium:
Bauch: Entzündete Gallenblase - chronisch
Brust: Schwäche im Herz + Lungen - Krebs - Atemnot
Allgemeines: Fettleibigkeit + unterentwickelten Genitalien
Repertory:
Xxxx
Important
Proving Symptoms and Themes Noted by the Investigators
Restless or
frequent waking
Eczema
(dry/flaky/< moisture) of the (r.) hand/fingers,
Mind: Active thoughts causes
sleeplessness
Absence of
thoughts - when alone/driving - startles when awareness returns
Vacancy of
thought/must force the mind to concentrate while driving
Day
dreaming
Memory
weak/forgets what is about to do/has just done
Feeling of
being in trance/”As if in a dream”
Dull
Dreams –
vivid/fragments/nightmares
(darkness/desolation/bleakness/destruction/imprisonment/among
strangers/violence/being whipped)
“As if
isolated or separated”
Delusions –
friends looking down
Confidence
in self
Strong
irritability when skin lightly stroked/touched.
Nail-biting
Generalities: Physical energy increased and
sleep decreased
Food:
Desires: cold cereal/meat (hamburger with cheese)
Flushes of
heat during the night requiring blankets
removed and replaced several times
Head: Chronic daily pain – “As if a
band”/pressing
Pain -
sudden/sinus headache during menses
Eye: Photophobia during daytime causing
squinting
Vision: Foggy and incoordinated
Nose: Epistaxis r. sided with bright
blood on blowing the nose
Coryza r.
sided
Postnasal bloody
discharge
Mouth: Dry with thirst
Sore gums
and tongue
Tongue –
indented/”As if swollen”/”As if too large”
Teeth: Pain – stitching while eating
Throat: Eruptions – “Like boils” on
opposite sides of neck in same size and location
External
throat: “As if
swollen”/”As if burning” in trachea after running a short distance.
Stomach: Appetite - decreased during
pain/lost after few bites
“As if
full”
Heartburn –
daily/morning acid
Thirsty
Abdomen: Distended - before menses/in the
afternoon
Pain – clutching/cramping
ext. middle of back
Pain -
before/during menses
Rectum: Evacuation feels incomplete after
straining
Diarrhea -
urgent and sudden/after eating/anticipatory
Flatus [and
diarrhea (before a sports competition)]
Pain -
cramping before stool
Stool: Sudden and explosive
Watery
Female
Genitalia: Bloody
discharge preceding onset of menses
Menses 1.
stops suddenly, followed by swollen fingers/face/breasts; 2. Menses begins
again shortly thereafter
Painful,
aching menstrual cramps
Respiration:
Speech and
Voice: hoarse and husky
Clearing
throat improves hoarseness that prevented speech
Back: Abdominal cramps ext. thoracic
region
Lower back
stiff on motion after sitting > heat
Limbs: Stiff > heat
Eczema -
eruptions on fingers/(palm) hand/painful: stinging/burning/itching/desquamating/only
r. hand < with moisture/flaky/white/dry
Fingers
sensitive (pressure)/shriveled/appearing small with eczema
Perspiration
in palm of hand with eczema
Itchy red
rash in hollow of knee
Dropping
objects “As from lack of hand-eye coordination
Sleep: Falling asleep difficult (after
waking)
Perspiration
during sleep
Restless/tossing
and turning/unrefreshing
Sleepless
from thoughts
Frequent
sudden waking
Perspiration: During sleep matting hair and
soaks the pillow
Skin: Eczema see Limbs
Allerlei: In hautaufhellende Cremes gebraucht
Parabenzoquinonum
Repertorium:
Gemüt: Eigensinnig, starr-/dickköpfig (Kinder)
Streitsüchtig (bei Alkoholikern)
Ungehorsam (Kindern)/Verhaltensstörungen (Kindern)
Auge: Degenerierte Netzhaut
Bauch: Leber entzündet
Verletzungen des Milzes
Nieren: Addison Syndrom
Atmung: Atemnot, Dyspnoe, erschwertes Atmen
Brust: Entzündete Endokard und Myokard
Glieder: Entzündet Gelenke - wandernd
Allgemeines: Multiple Sklerose
Osteochondrosis
Osteogenesis imperfecta tarda
Schwäche nach Bluttransfusion
Nebenniereninsuffizienz
Resorcinum (Res) = C6H6O2
Gebrauch: Taubheit/SCHWEIß/giddiness/salivation/convulsions;
Repertorium:
Magen: Erbricht während Durchfall
Rektum: Cholera infantum
Uitwendige toepassing als antiseptisch en desinfecterend
middel. Chronische huidaandoeningen: 5 - 10% in zalf bij psoriasis,
hidradenitis suppurativa, eczeem. Zelfzorg anti-Acne-middelen: 2%. Weak, watery solutions of resorcinol
(25 to 35 g/kg) allay itching in erythematous eczema. A 2% solution as a spray
in hay fever/whooping cough (0.6 ml of the 2% solution internally). As an
anti-dandruff agent in shampoo or in sunscreen cosmetics. It has also been
employed in the treatment of gastric ulcers in doses of 125 to 250 mg in pills,
and is said to be analgesic and haemostatic in its action.
Thymolum (Thymol)
Vorwort/Suchen Zeichen/Abkürzungen Impressum